Advances in Organometallic Chemistry, Vol. 55 by Robert C. West, Anthony F. Hill, Mark J. Fink PDF

By Robert C. West, Anthony F. Hill, Mark J. Fink

ISBN-10: 0123739780

ISBN-13: 9780123739780

Just about all branches of chemistry and fabric technological know-how now interface with organometallic chemistry - the examine of compounds containing carbon-metal bonds. This commonly acclaimed serial comprises authoritative stories that tackle all features of organometallic chemistry, a box which has extended greatly because the booklet of quantity 1 in 1964.* presents an authoritative, definitive evaluate addressing all features of organometallic chemistry* worthy to researchers inside of this energetic box and is a needs to for each sleek library of chemistry* top of the range study e-book inside of this quickly constructing box

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Additional info for Advances in Organometallic Chemistry, Vol. 55

Sample text

Murai et al. 207 Thus, the total body of evidence for a modified Chalk–Harrod mechanism followed by a number of Group VIII metals (except Pt) in hydrosilation catalysis is overwhelming. In 1998 Ozawa et al. 209 Over the last 10 years Ozawa and coworkers have investigated the catalytic aspects of hydrosilation in great and fine detail. 211 The large body of mechanistic work with the less active catalytic transition metals has been instrumental to broadening understanding of not only hydrosilation but also the closely related and important reaction dehydrogenative silylation.

Despite this limited success, the catalysis represents an important step forward in the hydrosilation of acrylates, which had only yielded mixtures of a- and b-adducts with all previously tested catalysts. K. , 25) to catalyze the hydrosilation of hindered and functionalized ketones with Et3SiH was very recently described by Nolan and coworkers [Eq. 106 Functionalities on the ketone substrate such as halide, ether and tertiary amine are well tolerated and excellent conversions are achievable using a number of variations of 25 (pre-synthesized or generated in situ) with different N-substitution on the ring.

Methyl methacrylate gave much lower yields, and triethylsilane or triethoxysilane failed to react. Despite this limited success, the catalysis represents an important step forward in the hydrosilation of acrylates, which had only yielded mixtures of a- and b-adducts with all previously tested catalysts. K. , 25) to catalyze the hydrosilation of hindered and functionalized ketones with Et3SiH was very recently described by Nolan and coworkers [Eq. 106 Functionalities on the ketone substrate such as halide, ether and tertiary amine are well tolerated and excellent conversions are achievable using a number of variations of 25 (pre-synthesized or generated in situ) with different N-substitution on the ring.

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Advances in Organometallic Chemistry, Vol. 55 by Robert C. West, Anthony F. Hill, Mark J. Fink


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